Отправить статью по E-mail Visible and near-IR spectroscopy of endohedral Gd@C82(C2v) and Ho@C82(C2v) metallofullerenes and their monoanions
- Авторы: Kareev I.E.1, Nekrasov V.M.1,2, Dutlov A.E.1,2, Martynenko V.M.1, Bubnov V.P.1, Laukhina E.3, Veciana J.3, Rovira C.3
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Учреждения:
- Institute of Problems of Chemical Physics
- Faculty of Fundamental Physical and Chemical Engineering
- Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)
- Выпуск: Том 91, № 3 (2017)
- Страницы: 536-542
- Раздел: Structure of Matter and Quantum Chemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/169345
- DOI: https://doi.org/10.1134/S0036024417030104
- ID: 169345
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Аннотация
Solutions of endohedral Gd@C82(C2v) and Ho@C82(C2v) metallofullerenes are studied by means of visible and near-IR spectroscopy upon their conversion from neutral to the anionic form via a redox reaction with the electron donor potassium perchlorotriphenylmethide K(18-crown-6)[C(C6Cl5)3]. The concentrations of the studied solutions of endohedral Gd@C82(C2v) and Ho@C82(C2v) metallofullerenes in o-dichlorobenzene were determined from the spectroscopic data, and their molar extinction coefficients are calculated.
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I. Kareev
Institute of Problems of Chemical Physics
Автор, ответственный за переписку.
Email: kareev@icp.ac.ru
Россия, Chernogolovka, Moscow oblast, 142432
V. Nekrasov
Institute of Problems of Chemical Physics; Faculty of Fundamental Physical and Chemical Engineering
Email: kareev@icp.ac.ru
Россия, Chernogolovka, Moscow oblast, 142432; Moscow, 119991
A. Dutlov
Institute of Problems of Chemical Physics; Faculty of Fundamental Physical and Chemical Engineering
Email: kareev@icp.ac.ru
Россия, Chernogolovka, Moscow oblast, 142432; Moscow, 119991
V. Martynenko
Institute of Problems of Chemical Physics
Email: kareev@icp.ac.ru
Россия, Chernogolovka, Moscow oblast, 142432
V. Bubnov
Institute of Problems of Chemical Physics
Email: kareev@icp.ac.ru
Россия, Chernogolovka, Moscow oblast, 142432
E. Laukhina
Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)
Email: kareev@icp.ac.ru
Испания, Bellaterra, 08193
J. Veciana
Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)
Email: kareev@icp.ac.ru
Испания, Bellaterra, 08193
C. Rovira
Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)
Email: kareev@icp.ac.ru
Испания, Bellaterra, 08193
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