Visible and near-IR spectroscopy of endohedral Gd@C82(C2v) and Ho@C82(C2v) metallofullerenes and their monoanions


Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Solutions of endohedral Gd@C82(C2v) and Ho@C82(C2v) metallofullerenes are studied by means of visible and near-IR spectroscopy upon their conversion from neutral to the anionic form via a redox reaction with the electron donor potassium perchlorotriphenylmethide K(18-crown-6)[C(C6Cl5)3]. The concentrations of the studied solutions of endohedral Gd@C82(C2v) and Ho@C82(C2v) metallofullerenes in o-dichlorobenzene were determined from the spectroscopic data, and their molar extinction coefficients are calculated.

Авторлар туралы

I. Kareev

Institute of Problems of Chemical Physics

Хат алмасуға жауапты Автор.
Email: kareev@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432

V. Nekrasov

Institute of Problems of Chemical Physics; Faculty of Fundamental Physical and Chemical Engineering

Email: kareev@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432; Moscow, 119991

A. Dutlov

Institute of Problems of Chemical Physics; Faculty of Fundamental Physical and Chemical Engineering

Email: kareev@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432; Moscow, 119991

V. Martynenko

Institute of Problems of Chemical Physics

Email: kareev@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432

V. Bubnov

Institute of Problems of Chemical Physics

Email: kareev@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432

E. Laukhina

Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)

Email: kareev@icp.ac.ru
Испания, Bellaterra, 08193

J. Veciana

Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)

Email: kareev@icp.ac.ru
Испания, Bellaterra, 08193

C. Rovira

Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)

Email: kareev@icp.ac.ru
Испания, Bellaterra, 08193

Қосымша файлдар

Қосымша файлдар
Әрекет
1. JATS XML
Жүктеу

© Pleiades Publishing, Ltd., 2017