Thermodynamic properties of liquid copper–lanthanum alloys

Resumo

Mixing enthalpies of alloys in the Cu–La system are measured using isoperibolic calorimetry method over the ranges 0 < x_La < 0.185 at 1400–1430 K and 0.659 < x_La < 1 at 1370 K. They have moderate exothermic values over the whole concentration range and agree with literature data. Activities of the components, enthalpies and entropies of formation of intermetallics in this system, and its phase diagram are optimized using an ideal associated solution (IAS) model, and agree with most literature data. The updated thermodynamic properties can be used in further investigation of multicomponent systems based on the binary Cu–La.