Enviar artigo por via de e-mail Layers of cyclam-substituted PVC with sodium hydroxide aqua complexes with aza-crown ligands on cellulose tissue filled with active coal
- Autores: Fridman A.Y.1, Tsivadze A.Y.1, Morozova E.M.1, Sokolova N.P.1, Voloshchuk A.M.1, Petukhova G.A.1, Bardyshev I.I.1, Gorbunov A.M.1, Novikov A.K.1, Polyakova I.Y.1, Titova V.N.1, Yavich A.A.1, Petrova N.V.1
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Afiliações:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Edição: Volume 90, Nº 3 (2016)
- Páginas: 641-646
- Seção: Physical Chemistry of Surface Phenomena
- URL: https://bakhtiniada.ru/0036-0244/article/view/167929
- DOI: https://doi.org/10.1134/S0036024416030109
- ID: 167929
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Resumo
A material with an electrically ОН–-conductive porous layer of cyclam-substituted PVC filled with active coal containing NaOH aqua complexes with aza-crown ligands and cross-linked with the surface of cellulose tissue fibers has been synthesized. The structure of the material was studied. Its sorption capacity in vapors and liquid benzene and hexane, specific resistance, potential of ОН- transfer from solution to layer, and rate constants of ОН– travel in the layer of the material as an electrochemical bridge in vapors and liquid benzene and hexane were determined. The aqua complexes decomposed in the layer with formation of Н2 during the cathodic polarization of the bridge and О2 during the anodic polarization; the composition of the complexes was regenerated due to the motion of ОН–.
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Sobre autores
A. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
E. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
N. Sokolova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
A. Voloshchuk
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
G. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
I. Bardyshev
Frumkin Institute of Physical Chemistry and Electrochemistry
Autor responsável pela correspondência
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
A. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
A. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
I. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
V. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
N. Petrova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Rússia, Moscow
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