Email this article Formation of a new adduct based on fullerene tris-malonate samarium salt С60–[C60(=C(COO)2)3]Sm2
- Authors: Petrov A.A.1, Keskinov V.A.2, Semenov K.N.2,3, Charykov N.A.2, Letenko D.G.4, Nikitin V.A.5
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Affiliations:
- St. Petersburg State Technological Institute
- PAO NPO Tekhnologii
- St. Petersburg State University
- St. Petersburg State University of Architecture and Civil Engineering
- Peter the Great Polytechnic University
- Issue: Vol 91, No 3 (2017)
- Pages: 549-554
- Section: Physical Chemistry of Nanoclusters and Nanomaterials
- URL: https://bakhtiniada.ru/0036-0244/article/view/169349
- DOI: https://doi.org/10.1134/S0036024417030207
- ID: 169349
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Abstract
Gram quantities of a new adduct based on light fullerene tris-malonate samarium salt С60 [C60(=C(COO)2)3]Sm2 are obtained via the reaction of ion exchange. The obtained adduct is studied by means of electron and infrared spectroscopy, X-ray and elemental analysis, electron microscopy, and thermogravimetry. The polythermal solubility of [C60(=C(COO)2)3]Sm2 in water is determined in ampoules via saturation within 20–70°C. The composition of crystalline hydrate [C60(=C(COO)2)3]Sm2 · 36Н2О, which exists in equilibrium with the saturated solution, is estimated.
About the authors
A. A. Petrov
St. Petersburg State Technological Institute
Author for correspondence.
Email: project2016@mail.ru
Russian Federation, St. Petersburg, 190013
V. A. Keskinov
PAO NPO Tekhnologii
Email: project2016@mail.ru
Russian Federation, St. Petersburg, 199178
K. N. Semenov
PAO NPO Tekhnologii; St. Petersburg State University
Email: project2016@mail.ru
Russian Federation, St. Petersburg, 199178; St. Petersburg, 199034
N. A. Charykov
PAO NPO Tekhnologii
Email: project2016@mail.ru
Russian Federation, St. Petersburg, 199178
D. G. Letenko
St. Petersburg State University of Architecture and Civil Engineering
Email: project2016@mail.ru
Russian Federation, St. Petersburg, 190005
V. A. Nikitin
Peter the Great Polytechnic University
Email: project2016@mail.ru
Russian Federation, St. Petersburg, 195251
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