Materials based on cellulose fabric and PVC with porous structures formed by jointed aza- and oxa-aza-crown macromolecules
- Авторлар: Fridman A.Y.1, Tsivadze A.Y.1, Morozova E.M.1, Sokolova N.P.1, Shiryaev A.A.1, Petukhova G.A.1, Voloshchuk A.M.1, Bardyshev I.I.1, Gorbunov A.M.1, Polyakova I.Y.1, Novikov A.K.1, Titova V.N.1, Yavich A.A.1, Petrova N.V.1
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Мекемелер:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Шығарылым: Том 90, № 12 (2016)
- Беттер: 2453-2458
- Бөлім: Physical Chemistry of Surface Phenomena
- URL: https://bakhtiniada.ru/0036-0244/article/view/169063
- DOI: https://doi.org/10.1134/S0036024416120104
- ID: 169063
Дәйексөз келтіру
Аннотация
A material with porous structures formed by jointed aza- and oxa-aza-crowns with peripheral OHgroups is synthesized on the basis of cellulose fabric and PVC transformed into hydroxyethylcyclam. Mesopores are mainly observed on the fiber surface. The specific surface of the material is 6 m2/g; the volume of free space is 0.112 cm3/g. Assuming the internal pores have a disk-like shape, their width is estimated at 2 nm. The material sorbs vapors of aliphatic and aromatic hydrocarbons, alcohols, aldehydes, ketones, amines, amides, nitriles, and sulfoxides. It also swells to a limited degree in organic solvents. When sulfuric acid or sodium hydroxide is sorbed in the pores, compounds of them with H+- and OH–-conducting systems of hydrogen bonds are formed.
Негізгі сөздер
Авторлар туралы
A. Fridman
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
E. Morozova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
N. Sokolova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Shiryaev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
G. Petukhova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Voloshchuk
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
I. Bardyshev
Frumkin Institute of Physical Chemistry and Electrochemistry
Хат алмасуға жауапты Автор.
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Gorbunov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
I. Polyakova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Novikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
V. Titova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
A. Yavich
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
N. Petrova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071
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