Materials based on cellulose fabric and PVC with porous structures formed by jointed aza- and oxa-aza-crown macromolecules


Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

A material with porous structures formed by jointed aza- and oxa-aza-crowns with peripheral OHgroups is synthesized on the basis of cellulose fabric and PVC transformed into hydroxyethylcyclam. Mesopores are mainly observed on the fiber surface. The specific surface of the material is 6 m2/g; the volume of free space is 0.112 cm3/g. Assuming the internal pores have a disk-like shape, their width is estimated at 2 nm. The material sorbs vapors of aliphatic and aromatic hydrocarbons, alcohols, aldehydes, ketones, amines, amides, nitriles, and sulfoxides. It also swells to a limited degree in organic solvents. When sulfuric acid or sodium hydroxide is sorbed in the pores, compounds of them with H+- and OH-conducting systems of hydrogen bonds are formed.

Авторлар туралы

A. Fridman

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

A. Tsivadze

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

E. Morozova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

N. Sokolova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

A. Shiryaev

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

G. Petukhova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

A. Voloshchuk

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

I. Bardyshev

Frumkin Institute of Physical Chemistry and Electrochemistry

Хат алмасуға жауапты Автор.
Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

A. Gorbunov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

I. Polyakova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

A. Novikov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

V. Titova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

A. Yavich

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

N. Petrova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: bardyshev@phyche.ac.ru
Ресей, Moscow, 119071

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