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Study on the catalytic activity of vanadium doped TiO2: Anatase-to-rutile phase transition


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Abstract

The catalytic activity of vanadium doped TiO2 in the ethylbenzene oxidative dehydrogenation with CO2 was studied experimentally and theoretically. The experimental results showed that the reduction of ethylbenzene conversion and the styrene selectivity was caused by the transition of anatase to rutile phase. Theoretical results showed that the transition of the anatase to rutile phase was mainly caused by vanadium ions and oxygen vacancies.

About the authors

Huiming Zhang

Department of Chemical Engineering

Author for correspondence.
Email: bzzhanghuiming@163.com
China, Binzhou, Shandong, 256603

He Bian

Department of Chemical Engineering

Email: bzzhanghuiming@163.com
China, Binzhou, Shandong, 256603

Shiguo Zhang

Department of Chemical Engineering

Email: bzzhanghuiming@163.com
China, Binzhou, Shandong, 256603

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