Catalytic Conversion of Glycerol in the Presence of Ni/F–Al2O3 Catalyst


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Abstract

It is shown that glycerol hydrogenation in the presence of Ni/F–Al2O3 catalyst leads to the formation of simple alcohols ethanol and propanol-1. The process consists of two simultaneously occurring stages: glycerol dehydration on the acid sites of the support and the hydrodeoxygenation of glycerol and propanediols formed as intermediates.

About the authors

A. A. Greish

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

Email: lmk@ioc.ac.ru
Russian Federation, Moscow, 119991

L. M. Kustov

Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences; Faculty of Chemistry, Moscow State University

Author for correspondence.
Email: lmk@ioc.ac.ru
Russian Federation, Moscow, 119991; Moscow, 119991

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