Email this article Carboxylation of 2-methylbutyn-3-ol-2 on Ag- and Cu-containing catalysts
- Authors: Finashina E.D.1, Kustov L.M.1,2, Krasovskii V.G.1, Formenova E.I.1
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Affiliations:
- Zelinskii Institute of Organic Chemistry
- Department of Chemistry
- Issue: Vol 90, No 9 (2016)
- Pages: 1729-1732
- Section: Chemical Kinetics and Catalysis
- URL: https://bakhtiniada.ru/0036-0244/article/view/168678
- DOI: https://doi.org/10.1134/S0036024416090089
- ID: 168678
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Abstract
The analysis of the products of direct carboxylation of 2-methylbutyn-3-ol-2 with carbon dioxide on Ag- and Cu-containing catalysts by 1Н and 13С NMR and FTIR spectroscopy showed that the desired 4-hydroxy-4-methylpent-2-ynoic acid did not form under the given conditions; instead, the triple bond of the substrate decomposed, and two polyfunctional acids formed: 4-hydroxy-4-methyl-3-oxopentanoic and 3,4-dihydroxy-4-methylpent-2-enic (the latter is the result of the keto-enol rearrangement of the former keto acid).
About the authors
E. D. Finashina
Zelinskii Institute of Organic Chemistry
Author for correspondence.
Email: finesta@mail.ru
Russian Federation, Moscow
L. M. Kustov
Zelinskii Institute of Organic Chemistry; Department of Chemistry
Email: finesta@mail.ru
Russian Federation, Moscow; Moscow
V. G. Krasovskii
Zelinskii Institute of Organic Chemistry
Email: finesta@mail.ru
Russian Federation, Moscow
E. I. Formenova
Zelinskii Institute of Organic Chemistry
Email: finesta@mail.ru
Russian Federation, Moscow
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