Phase Diagram of the Nicotinic Acid + Ammonium Sulfate + Water System
- Authors: Yanfei Wang 1, Hu J.1, Zhao X.1, Liu X.1, Chen Z.1, Liu Z.1, Yang L.1, Zhu L.1, Sha Z.1
-
Affiliations:
- Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology
- Issue: Vol 92, No 13 (2018)
- Pages: 2612-2617
- Section: Chemical Thermodynamics and Thermochemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/170275
- DOI: https://doi.org/10.1134/S003602441813037X
- ID: 170275
Cite item
Abstract
The solid–liquid equilibria (SLE) in the ternary nicotinic acid + ammonium sulfate + water system were experimentally studied at T = 298.15, 323.15, and 348.15 K under atmospheric pressure by an isothermal equilibrium method. Three isothermal phase diagrams of the system were established based on the measured mutual solubility data. Meanwhile, the physicochemical properties (density and conductivity) of this system were measured. The phase diagram contained three crystallization regions, two crystallization curves, and one co-saturation point at each temperature. The crystallization field of both nicotinic acid and ammonium sulfate enlarged with increase of temperature. The crystallization region of ammonium sulfate was smaller than that of nicotinic acid at each temperature.
About the authors
Yanfei Wang
Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science,Tianjin University of Science and Technology
Email: xyz@tust.edu.cn
China, Tianjin, 300457
Jiaqi Hu
Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science,Tianjin University of Science and Technology
Email: xyz@tust.edu.cn
China, Tianjin, 300457
Xiaoyu Zhao
Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science,Tianjin University of Science and Technology
Author for correspondence.
Email: xyz@tust.edu.cn
China, Tianjin, 300457
Xiaoyu Liu
Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science,Tianjin University of Science and Technology
Email: xyz@tust.edu.cn
China, Tianjin, 300457
Zhao Chen
Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science,Tianjin University of Science and Technology
Email: xyz@tust.edu.cn
China, Tianjin, 300457
Zongjing Liu
Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science,Tianjin University of Science and Technology
Email: xyz@tust.edu.cn
China, Tianjin, 300457
Libin Yang
Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science,Tianjin University of Science and Technology
Email: xyz@tust.edu.cn
China, Tianjin, 300457
Liang Zhu
Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science,Tianjin University of Science and Technology
Email: xyz@tust.edu.cn
China, Tianjin, 300457
Zuoliang Sha
Tianjin Key Laboratory of Marine Resources and Chemistry, College of Chemical Engineering and Materials Science,Tianjin University of Science and Technology
Email: xyz@tust.edu.cn
China, Tianjin, 300457
Supplementary files
