电邮这篇文章 Rhodium Catalyst–Ionic Liquids Interaction by X-ray Photoelectron Spectroscopy Data
- 作者: Yujuan Jin 1, Shuang Men 2
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隶属关系:
- School of Materials and Mechanical Engineering Beijing Technology and Business University
- School of Material Science and Engineering Shenyang Ligong University
- 期: 卷 92, 编号 12 (2018)
- 页面: 2472-2475
- 栏目: Chemical Kinetics and Catalysis
- URL: https://bakhtiniada.ru/0036-0244/article/view/170251
- DOI: https://doi.org/10.1134/S0036024418120361
- ID: 170251
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详细
We investigate the Schrock–Osborn catalyst, [Rh(COD)(PPh3)2][PF6], in a series of ionic liquids by XPS. The electronic environment of the rhodium centre is demonstrated. The subtle change of the electronic environment of the rhodium centre due to the catalyst-ionic liquids interaction is revealed based upon Rh 3d binding energy. It suggests that the anion of ionic liquids can have significant impact on the electronic environment of the rhodium centre.
作者简介
Yujuan Jin
School of Materials and Mechanical Engineering Beijing Technology and Business University
编辑信件的主要联系方式.
Email: jinyujuan@th.btbu.edu.cn
中国, Beijing
Shuang Men
School of Material Science and Engineering Shenyang Ligong University
Email: jinyujuan@th.btbu.edu.cn
中国, Shenyang
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