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Liquid–Liquid Equilibrium Study in the n-Heptane + Phenol + Sulfolane Ternary System


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Abstract

Liquid–liquid equilibrium data for the n-heptane + phenol + sulfolane system were obtained at 323.15 and 343.15 K under 101.35 kPa pressure. The distribution coefficient (K) and separation factor (S) were calculated to assess the effectiveness of extracting phenol from n-heptane, and the consistency of LLE date were verified by the Othmer–Tobias, Hand as well as Bachman equations. The experimental data were correlated by using NRTL and UNIQUAC models, and the root-mean-square deviation (RMSD) values of both models were below 0.59%, demonstrating the two models were successfully describe the experimental data.

About the authors

Yan Lv

College of Chemical Engineering, East China University of Science and Technology

Author for correspondence.
Email: fen-xi@hotmail.com
China, Shanghai, 200237

Weichang Ding

College of Chemical Engineering, East China University of Science and Technology

Email: fen-xi@hotmail.com
China, Shanghai, 200237

Li Liang

College of Chemical Engineering, East China University of Science and Technology

Email: fen-xi@hotmail.com
China, Shanghai, 200237

Qian Jia

College of Chemical Engineering, East China University of Science and Technology

Email: fen-xi@hotmail.com
China, Shanghai, 200237

Xiaoyi Liang

College of Chemical Engineering, East China University of Science and Technology

Email: fen-xi@hotmail.com
China, Shanghai, 200237

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