Email this article Kinetic Features of the Formation of Zinc Complex with Hexa(m-Trifluoromethylphenyl)benzoporphyrazine in a Nitrogen-Containing Base–Benzene System
- Authors: Petrov O.A.1
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Affiliations:
- Ivanovo State University of Chemical Technology
- Issue: Vol 92, No 9 (2018)
- Pages: 1664-1669
- Section: Chemical Kinetics and Catalysis
- URL: https://bakhtiniada.ru/0036-0244/article/view/170113
- DOI: https://doi.org/10.1134/S0036024418090200
- ID: 170113
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Abstract
The effect n-butylamine, tert-butylamine, piperidine, and morpholine additives have on the kinetics of complex formation between zinc acetate and hexa(m-trifluoromethylphenyl)benzoporphyrazine in benzene is studied. A possible scheme for their complexation is proposed. It is established that the rate and activation parameters of the process are affected by the proton-acceptor capacity of the base and its spatial structure.
About the authors
O. A. Petrov
Ivanovo State University of Chemical Technology
Author for correspondence.
Email: poa@isuct.ru
Russian Federation, Ivanovo, 153000
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