Selective Hydrogenation of Acetylene and Physicochemical Properties of Pd–Fe/Al2O3 Bimetallic Catalysts


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Abstract

The selective hydrogenation of acetylene on Pd–Fe/Al2O3 catalysts prepared by decomposition of ferrocene on reduced Pd/Al2O3 was studied. The effect of the conditions of treatment of the Pd–ferrocene/ Al2O3 precursor on the catalyst activity and selectivity was investigated, and the optimum conditions were determined at which the Pd–Fe/Al2O3 catalyst has higher selectivity than Pd/Al2O3 without any loss of activity.

About the authors

V. D. Stytsenko

Gubkin Russian State University of Oil and Gas

Author for correspondence.
Email: vds41@mail.ru
Russian Federation, Moscow

D. P. Mel’nikov

Gubkin Russian State University of Oil and Gas

Email: vds41@mail.ru
Russian Federation, Moscow

O. P. Tkachenko

Zelinskii Institute of Organic Chemistry

Email: vds41@mail.ru
Russian Federation, Moscow

E. V. Savel’eva

Gubkin Russian State University of Oil and Gas

Email: vds41@mail.ru
Russian Federation, Moscow

A. P. Semenov

Gubkin Russian State University of Oil and Gas

Email: vds41@mail.ru
Russian Federation, Moscow

L. M. Kustov

Zelinskii Institute of Organic Chemistry

Email: vds41@mail.ru
Russian Federation, Moscow

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