Selective Hydrogenation of Acetylene and Physicochemical Properties of Pd–Fe/Al 2 O 3  Bimetallic Catalysts

V. D. Stytsenko; D. P. Mel’nikov; O. P. Tkachenko; E. V. Savel’eva; A. P. Semenov; L. M. Kustov

doi:10.1134/S0036024418050308

Selective Hydrogenation of Acetylene and Physicochemical Properties of Pd–Fe/Al₂O₃ Bimetallic Catalysts

Authors: Stytsenko V.D.¹, Mel’nikov D.P.¹, Tkachenko O.P.², Savel’eva E.V.¹, Semenov A.P.¹, Kustov L.M.²
Affiliations:
1. Gubkin Russian State University of Oil and Gas
2. Zelinskii Institute of Organic Chemistry
Issue: Vol 92, No 5 (2018)
Pages: 862-869
Section: Chemical Kinetics and Catalysis
URL: https://bakhtiniada.ru/0036-0244/article/view/169989
DOI: https://doi.org/10.1134/S0036024418050308
ID: 169989

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Abstract

The selective hydrogenation of acetylene on Pd–Fe/Al₂O₃ catalysts prepared by decomposition of ferrocene on reduced Pd/Al₂O₃ was studied. The effect of the conditions of treatment of the Pd–ferrocene/ Al₂O₃ precursor on the catalyst activity and selectivity was investigated, and the optimum conditions were determined at which the Pd–Fe/Al₂O₃ catalyst has higher selectivity than Pd/Al₂O₃ without any loss of activity.