Kinetics and Mechanism of the Oxidative Conversion of n-Amyl Alcohol to Valeric Acid on a Modified Zeolite Catalyst


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The catalytic activity of natural and synthetic mordenites modified with Cu2+, Zn2+, and Pd2+ cations via ion exchange was studied in the oxidative conversion of n-amyl alcohol to valeric acid under the action of oxygen. It is established that the highest activity and selectivity in this reaction is exhibited by mordenite hydrothermally synthesized from kaolinite and containing 3.0 wt % Cu2+, 0.1 wt % Pd2+, and 2.0 wt % Zn2+. The kinetics of this catalytic reaction is studied. Based on the experimental data, a possible stepwise mechanism is proposed, and a theoretically grounded kinetic model of the process is developed.

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A. Aliev

Nagiev Institute of Catalysis and Inorganic Chemistry

编辑信件的主要联系方式.
Email: agil_s@mail.ru
阿塞拜疆, Baku, AZ1143

M. Bakhmanov

Nagiev Institute of Catalysis and Inorganic Chemistry

Email: agil_s@mail.ru
阿塞拜疆, Baku, AZ1143

F. Agaev

Nagiev Institute of Catalysis and Inorganic Chemistry

Email: agil_s@mail.ru
阿塞拜疆, Baku, AZ1143

V. Agaev

Nagiev Institute of Catalysis and Inorganic Chemistry

Email: agil_s@mail.ru
阿塞拜疆, Baku, AZ1143

Z. Shabanova

Nagiev Institute of Catalysis and Inorganic Chemistry

Email: agil_s@mail.ru
阿塞拜疆, Baku, AZ1143

A. Safarov

Nagiev Institute of Catalysis and Inorganic Chemistry

Email: agil_s@mail.ru
阿塞拜疆, Baku, AZ1143

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