Vibrational Satellites and Pseudorotation in 2-Methyl-1,3-dioxolane
- Authors: Faizullin M.G.1, Galeev R.V.1, Mamleev A.K.1
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Affiliations:
- Institute of Molecule and Crystal Physics
- Issue: Vol 92, No 3 (2018)
- Pages: 482-487
- Section: Structure of Matter and Quantum Chemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/169927
- DOI: https://doi.org/10.1134/S0036024418030081
- ID: 169927
Cite item
Abstract
Vibrational satellites caused by pseudorotation are identified in the microwave spectrum of 2-methyl-1,3-dioxolane. The rotational constants of the satellites are determined up to state v = 6. Splittings between lower pseudorotational energy levels are determined by measuring the relative intensities of rotational transitions. An attempt is made to determine the form of the pseudorotation function of the molecule using the obtained data.
About the authors
M. G. Faizullin
Institute of Molecule and Crystal Physics
Author for correspondence.
Email: fayzullinmg@yandex.ru
Russian Federation, Ufa, 450075
R. V. Galeev
Institute of Molecule and Crystal Physics
Email: fayzullinmg@yandex.ru
Russian Federation, Ufa, 450075
A. Kh. Mamleev
Institute of Molecule and Crystal Physics
Email: fayzullinmg@yandex.ru
Russian Federation, Ufa, 450075
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