Photoinduced Oxidation of a Surface of CaV0.5Mo0.5O3 − δ


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CaV0.5Mo0.5O3 − δ with the structure of perovskite is synthesized in an atmosphere of humid hydrogen. It is found that when the material under study is moved into air, a nonequilibrium state forms due to the enhanced concentration of oxygen over the surface of the highly reduced oxide. It is shown that photoinitiated oxidation is observed on the surface of the material under the action of a low-power laser beam (50 mW), where it selectively occurs under a green laser beam (λ = 532 nm). This phenomenon is observed for such materials for the first time.

作者简介

S. Belyakov

Institute of High Temperature Electrochemistry, Ural Branch

编辑信件的主要联系方式.
Email: bca2@mail.ru
俄罗斯联邦, Yekaterinburg, 620137

S. Shkerin

Institute of High Temperature Electrochemistry, Ural Branch

Email: bca2@mail.ru
俄罗斯联邦, Yekaterinburg, 620137

M. Kuznetsov

Institute of Solid State Chemistry, Ural Branch

Email: bca2@mail.ru
俄罗斯联邦, Yekaterinburg, 620990

E. Vovkotrub

Institute of High Temperature Electrochemistry, Ural Branch

Email: bca2@mail.ru
俄罗斯联邦, Yekaterinburg, 620137

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