Thermodynamic Work of Separation in a Cascade System in Processing a Multicomponent Mixture


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Abstract

The possibility of calculating thermodynamic work of separation WT,K for a complex of cascades consisting of earlier described stages of equilibrium separation with semipermeable plungers is illustrated by the processing of a four-component mixture. It is found that work WT,K can be considered as sum ΣWT,Kmk, where WT,Kmk corresponds to selected pairs of components (m, k) in a multicomponent mixture. The proposed procedure for calculating WT,K is spread into combinations of 8, 16, or even more components, and into extraction and chromatographic systems of fractioning.

About the authors

V. P. Chizhkov

Zelinsky Institute of Organic Chemistry

Email: boysoft@orc.ru
Russian Federation, Moscow, 119991

V. N. Boitsov

Zelinsky Institute of Organic Chemistry

Author for correspondence.
Email: boysoft@orc.ru
Russian Federation, Moscow, 119991

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