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Thermodynamics of dissolved nitrogen, nitrous oxide, and ammonia in perfluorodecalin


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Abstract

The solubility of N2, N2O, and NН3 is studied in different organic solvents. The best dissolution (0.27 ppm) is found to be for N2O in perfluorodecalin at 291 K and a pressure of 99 kPa. The dependence of N2O solubility in perfluorodecalin on pressure is studied at 291 K. The Gibbs energy of the solubility of nitrogen, nitrous oxide, and ammonia in perfluorodecalin is calculated.

About the authors

A. V. Moshnyaga

Mendeleev University of Chemical Technology

Author for correspondence.
Email: alexeymoshnyaga@yandex.ru
Russian Federation, Moscow, 125047

A. V. Khoroshilov

Mendeleev University of Chemical Technology

Email: alexeymoshnyaga@yandex.ru
Russian Federation, Moscow, 125047

D. I. Selivanova

Mendeleev University of Chemical Technology

Email: alexeymoshnyaga@yandex.ru
Russian Federation, Moscow, 125047

D. M. Aksenova

Mendeleev University of Chemical Technology

Email: alexeymoshnyaga@yandex.ru
Russian Federation, Moscow, 125047

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