Structure of ruthenium(II) complexes with coproporphyrin I tetraethyl ester
- 作者: Zverev S.A.1,2, Andreev S.V.1,3, Zamilatskov I.A.1,2, Kurochkina N.M.1, Tyurin V.S.1, Senchikhin I.N.1, Ponomarev G.V.4, Erzina D.R.1,2, Chernyshev V.V.1,5
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隶属关系:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Institute of Fine Chemical Technologies
- Rospotrebnadzor Research Institute of Disinfectology
- Orekhovich Institute of Biomedical Chemistry
- Department of Chemistry
- 期: 卷 91, 编号 8 (2017)
- 页面: 1462-1467
- 栏目: Structure of Matter and Quantum Chemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/169660
- DOI: https://doi.org/10.1134/S0036024417080386
- ID: 169660
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详细
The reaction between coproporphyrin I tetraethyl ester and ruthenium(II) dodecacarbonyl in toluene is investigated. The formation of two different products, complexes 2 and 3 of ruthenium(II) with coproporphyrin I tetraethyl ester, studied by means of mass spectrometry, electronic absorption spectroscopy, NMR, X-ray diffraction, and thermogravimetric analysis, is revealed. Structures are proposed for the products, of which (2) is a monocarbonyl complex of ruthenium(II) porphyrin that exists as a coordination polymer formed owing to intermolecular axial bonding between the oxygen atoms of carboethoxyl groups and ruthenium(II). The structure proposed for second product (3) is in the form of the corresponding monomer of a monocarbonyl complex of ruthenium(II) porphyrin. It is established that polymeric complex 2 transforms into monomeric complex 3 when it is heating in pyridine.
作者简介
S. Zverev
Frumkin Institute of Physical Chemistry and Electrochemistry; Institute of Fine Chemical Technologies
Email: joz@mail.ru
俄罗斯联邦, Moscow, 199071; Moscow, 119454
S. Andreev
Frumkin Institute of Physical Chemistry and Electrochemistry; Rospotrebnadzor Research Institute of Disinfectology
Email: joz@mail.ru
俄罗斯联邦, Moscow, 199071; Moscow, 117246
I. Zamilatskov
Frumkin Institute of Physical Chemistry and Electrochemistry; Institute of Fine Chemical Technologies
编辑信件的主要联系方式.
Email: joz@mail.ru
俄罗斯联邦, Moscow, 199071; Moscow, 119454
N. Kurochkina
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: joz@mail.ru
俄罗斯联邦, Moscow, 199071
V. Tyurin
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: joz@mail.ru
俄罗斯联邦, Moscow, 199071
I. Senchikhin
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: joz@mail.ru
俄罗斯联邦, Moscow, 199071
G. Ponomarev
Orekhovich Institute of Biomedical Chemistry
Email: joz@mail.ru
俄罗斯联邦, Moscow, 119992
D. Erzina
Frumkin Institute of Physical Chemistry and Electrochemistry; Institute of Fine Chemical Technologies
Email: joz@mail.ru
俄罗斯联邦, Moscow, 199071; Moscow, 119454
V. Chernyshev
Frumkin Institute of Physical Chemistry and Electrochemistry; Department of Chemistry
Email: joz@mail.ru
俄罗斯联邦, Moscow, 199071; Moscow, 119991
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