Thermodynamics of the equilibrium of the reaction between (5,10,15,20-tetra(2-methoxyphenyl)porphinato)chloroindium(III) and pyridine
- Authors: Bichan N.G.1, Ovchenkova E.N.1, Mozhzhukhina E.G.1, Lomova T.N.1
-
Affiliations:
- Krestov Institute of Solution Chemistry
- Issue: Vol 91, No 7 (2017)
- Pages: 1279-1284
- Section: Structure of Matter and Quantum Chemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/169610
- DOI: https://doi.org/10.1134/S0036024417070068
- ID: 169610
Cite item
Abstract
The results from thermodynamic and quantum-chemical studies of the reversible reaction between (5,10,15,20-tetra(2-methoxyphenyl)porphinato)chloroindium(III) and pyridine are reported. The main physicochemical parameters of properties of its supramolecular products are obtained and analyzed. The addition of pyridine molecules to metalloporphyrin proceeds in one step to attain an equilibrium state with the formation of supramolecules with a stoichiometry of 2: 1; spectral characteristics and parameters of the stability of the latter are identified. The possibility of using substituted indium(III)porphyrin for further research in the field of hybrid solar cells is discussed.
About the authors
N. G. Bichan
Krestov Institute of Solution Chemistry
Email: tnl@isc-ras.ru
Russian Federation, Ivanovo, 153045
E. N. Ovchenkova
Krestov Institute of Solution Chemistry
Email: tnl@isc-ras.ru
Russian Federation, Ivanovo, 153045
E. G. Mozhzhukhina
Krestov Institute of Solution Chemistry
Email: tnl@isc-ras.ru
Russian Federation, Ivanovo, 153045
T. N. Lomova
Krestov Institute of Solution Chemistry
Author for correspondence.
Email: tnl@isc-ras.ru
Russian Federation, Ivanovo, 153045
Supplementary files
