Oxidation of ethanol on NaX zeolite modified with transition metals


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Аннотация

NaLaX, NaX + Co, and NaPdX catalysts are synthesized by modification of NaX zeolite with transition metals (La, Co, Pd). The activity of the prepared materials in catalytic ethanol oxidation is studied in the temperature range of 423–723 K. It is shown that NaPdX and NaX + Co accelerate the reactions of partial and complete oxidation of ethanol as the temperature rises. NaLaX accelerates both intramolecular and intermolecular dehydration of alcohol. It is shown that the NaPdX (1.0% Pd) sample has the highest activity in the complete oxidation of alcohol with the formation of CO2.

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Авторлар туралы

J. Mirzai

Azerbaijan State Oil and Industrial University

Email: parviznadirov@rambler.ru
Әзірбайжан, Baku, AZ100

P. Nadirov

Azerbaijan State Oil and Industrial University

Хат алмасуға жауапты Автор.
Email: parviznadirov@rambler.ru
Әзірбайжан, Baku, AZ100

A. Velieva

Azerbaijan State Oil and Industrial University

Email: parviznadirov@rambler.ru
Әзірбайжан, Baku, AZ100

V. Muradkhanli

Azerbaijan State Oil and Industrial University

Email: parviznadirov@rambler.ru
Әзірбайжан, Baku, AZ100

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