Oxidation of ethanol on NaX zeolite modified with transition metals
- Авторлар: Mirzai J.I.1, Nadirov P.A.1, Velieva A.D.1, Muradkhanli V.G.1
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Мекемелер:
- Azerbaijan State Oil and Industrial University
- Шығарылым: Том 91, № 6 (2017)
- Беттер: 1005-1009
- Бөлім: Chemical Thermodynamics and Thermochemistry
- URL: https://bakhtiniada.ru/0036-0244/article/view/169517
- DOI: https://doi.org/10.1134/S0036024417060164
- ID: 169517
Дәйексөз келтіру
Аннотация
NaLaX, NaX + Co, and NaPdX catalysts are synthesized by modification of NaX zeolite with transition metals (La, Co, Pd). The activity of the prepared materials in catalytic ethanol oxidation is studied in the temperature range of 423–723 K. It is shown that NaPdX and NaX + Co accelerate the reactions of partial and complete oxidation of ethanol as the temperature rises. NaLaX accelerates both intramolecular and intermolecular dehydration of alcohol. It is shown that the NaPdX (1.0% Pd) sample has the highest activity in the complete oxidation of alcohol with the formation of CO2.
Авторлар туралы
J. Mirzai
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
Әзірбайжан, Baku, AZ100
P. Nadirov
Azerbaijan State Oil and Industrial University
Хат алмасуға жауапты Автор.
Email: parviznadirov@rambler.ru
Әзірбайжан, Baku, AZ100
A. Velieva
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
Әзірбайжан, Baku, AZ100
V. Muradkhanli
Azerbaijan State Oil and Industrial University
Email: parviznadirov@rambler.ru
Әзірбайжан, Baku, AZ100
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