Email this article Quantum chemical study of the rearrangement of phenoxyl-hydroxyphenyl radicals
- Authors: Porkhun V.I.1, Aristova Y.V.1, Porkhun E.V.1
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Affiliations:
- Volgograd State Technical University
- Issue: Vol 91, No 3 (2017)
- Pages: 472-475
- Section: Chemical Kinetics and Catalysis
- URL: https://bakhtiniada.ru/0036-0244/article/view/169318
- DOI: https://doi.org/10.1134/S0036024417030220
- ID: 169318
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Abstract
The absorption spectra and decomposition kinetics of intermediates formed upon the photolysis of p-iodophenol are studied via flash photolysis. The extinction coefficient of the p-iodophenoxyl radical is calculated. It is found that p-iodophenol acts as an inhibitor of light-independent liquid-phase oxidation reactions.
About the authors
V. I. Porkhun
Volgograd State Technical University
Email: arisjulia@yandex.ru
Russian Federation, 400005
Yu. V. Aristova
Volgograd State Technical University
Author for correspondence.
Email: arisjulia@yandex.ru
Russian Federation, 400005
E. V. Porkhun
Volgograd State Technical University
Email: arisjulia@yandex.ru
Russian Federation, 400005
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