Thermal decomposition of solid solutions in systems of Fe(II), Co(II), and Ni(II) hydrogen maleates with the formation of bimetallic nanoparticles


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详细

XRD phase analysis and thermal analysis are used to confirm the formation of a continuous series of solid solutions in which one cation is substituted for another in the systems Co(II) hydrogen maleate–Ni(II) hydrogen maleate; Fe(II) hydrogen maleate–Co(II) hydrogen maleate; and Fe(II) hydrogen maleate–Ni(II) hydrogen maleate. The unit cell volume of these solid solutions is shown to depend linearly on their composition. The linear character of changes in the initial temperatures of dehydration and thermal decomposition is established. Using the example of the first of these systems, it is shown that when heated, bimetallic nanoparticles embedded in the polymeric matrix of composites obtained via the thermal decomposition of solid solutions of hydrogen maleates undergo a second-order phase transition, resulting in decomposition of the solid solutions of metals at the Curie temperature.

作者简介

L. Yudanova

Nikolaev Institute of Inorganic Chemistry

编辑信件的主要联系方式.
Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

V. Logvinenko

Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University

Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090

L. Sheludyakova

Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University

Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090

A. Ishchenko

Institute of Catalysis; Novosibirsk State University

Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090

N. Rudina

Institute of Catalysis

Email: judanova@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

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