Metastable Equilibria with the Participation of Superheated Crystal Phases in Binary Oxide Systems


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Experimental diagrams of binary systems, including compounds that melt upon decomposition, sometimes display the metastable congruent melting of such compounds above the peritectic equilibrium temperature. Conditions in which the occurrence of superheated states of binary systems is possible are analyzed. Thermodynamic and kinetic interpretations of such phenomena are presented.

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V. Kosyakov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch

编辑信件的主要联系方式.
Email: vsh@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

V. Shestakov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University of Architecture and Civil Engineering

Email: vsh@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630008

A. Kaplun

Kutateladze Institute of Thermophysics, Siberian Branch

Email: vsh@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

A. Meshalkin

Kutateladze Institute of Thermophysics, Siberian Branch

Email: vsh@niic.nsc.ru
俄罗斯联邦, Novosibirsk, 630090

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