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Characteristics of a chain thermal explosion as a function of the kinetic properties of reaction chains


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Abstract

Study of the combustion and explosion of hydrogen‒carbon oxide‒air mixtures shows that the sharpness of a chain thermal explosion depends on the frequency of branching in a given branch of a reaction chain. It is established that varying the СО: Н2 concentration allows us to observe and eliminate the degeneration of an explosion while maintaining the regimes of ignition and deflagration.

About the authors

V. V. Azatyan

Institute of Structural Macrokinetics and Materials Science

Author for correspondence.
Email: azatyan@ism.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

A. A. Piloyan

Nalbandyan Institute of Chemical Physics

Email: azatyan@ism.ac.ru
Armenia, Yerevan, 0044

G. R. Saikova

Institute of Structural Macrokinetics and Materials Science

Email: azatyan@ism.ac.ru
Russian Federation, Chernogolovka, Moscow oblast, 142432

N. N. Smirnov

Institute of Mechanics

Email: azatyan@ism.ac.ru
Russian Federation, Moscow, 119991

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