Catalytic performance of V2O5–MoO3/γ-Al2O3 catalysts for partial oxidation of n-hexane1
- 作者: Mahmoudian R.1, Khodadadi Z.2, Mahdavi V.3, Salehi M.4
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隶属关系:
- Shazand Petrochemical Co
- Department of Applied Chemistry, Basic Science Faculty, South Tehran Branch
- Department of Chemistry, Science Faculty
- S.T. Petrochemical Co
- 期: 卷 90, 编号 1 (2016)
- 页面: 65-71
- 栏目: Chemical Kinetics and Catalysis
- URL: https://bakhtiniada.ru/0036-0244/article/view/167551
- DOI: https://doi.org/10.1134/S0036024416010180
- ID: 167551
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In the current study, a series of V2O5–MoO3 catalyst supported on γ-Al2O3 with various V2O5 and MoO3 loadings was prepared by wet impregnation technique. The characterization of prepared catalysts includes BET surface area, powder X-ray diffraction (XRD), and oxygen chemisorptions. The partial oxidation of n-hexane by air over V2O5–MoO3/γ-Al2O3 catalysts was carried out under flow condition in a fixed bed glass reactor. The effect of V2O5 loading, temperature, MoO3 loading, and n-hexane LHSV on the n-hexane conversion and the product selectivity were investigated. The partial oxygenated products of n-hexane oxidation were ethanol, acetic anhydride, acetic acid, and acetaldehyde. The 10% V2O5–1%MoO3/γ-Al2O3 was found in most active and selective catalyst during partial oxidation of n-hexane. The results indicated that by increasing the temperature, the n-hexane conversion increases as well, although the selectivity of the products passes through a maximum by increasing the temperature.
作者简介
R. Mahmoudian
Shazand Petrochemical Co
Email: za_khd@yahoo.com
伊朗伊斯兰共和国, Arak
Z. Khodadadi
Department of Applied Chemistry, Basic Science Faculty, South Tehran Branch
编辑信件的主要联系方式.
Email: za_khd@yahoo.com
伊朗伊斯兰共和国, Tehran
Vahid Mahdavi
Department of Chemistry, Science Faculty
Email: za_khd@yahoo.com
伊朗伊斯兰共和国, Arak
Mohammed Salehi
S.T. Petrochemical Co
Email: za_khd@yahoo.com
伊朗伊斯兰共和国, Mahshahr
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