Отправить статью по E-mail Reaction of the [B10H9O2C4H8]– anion with C-nucleophiles
- Авторы: Matveev E.Y.1,2, Akimov S.S.3, Kubasov A.S.1, Nichugovskii A.I.2, Nartov A.S.4, Retivov V.M.4, Zhizhin K.Y.1,2, Kuznetsov N.T.1
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry
- Moscow Technological University (MITHT)
- Chimmed Ltd.
- Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”
- Выпуск: Том 62, № 6 (2017)
- Страницы: 808-813
- Раздел: Physical Methods of Investigation
- URL: https://bakhtiniada.ru/0036-0236/article/view/167769
- DOI: https://doi.org/10.1134/S0036023617060146
- ID: 167769
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Аннотация
The reactions of 1,4-dioxane-substituted closo-decaborate anion ([B10H9O2C4H8]–) with metal acetylenides, diethyl malonate, ethyl acetoacetate, triethyl orthoformate, acetylacetone, and malonodinitrile were studied. The reactions were shown to be accompanied with substituent ring opening and attachment of the corresponding pendant functional group. The obtained compounds were characterized by various physicochemical methods (IR and polynuclear NMR spectroscopy, ESI mass spectrometry).
Об авторах
E. Matveev
Kurnakov Institute of General and Inorganic Chemistry; Moscow Technological University (MITHT)
Email: zhizhin@igic.ras.ru
Россия, Moscow, 117907; Moscow, 119571
S. Akimov
Chimmed Ltd.
Email: zhizhin@igic.ras.ru
Россия, Moscow, 115230
A. Kubasov
Kurnakov Institute of General and Inorganic Chemistry
Email: zhizhin@igic.ras.ru
Россия, Moscow, 117907
A. Nichugovskii
Moscow Technological University (MITHT)
Email: zhizhin@igic.ras.ru
Россия, Moscow, 119571
A. Nartov
Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”
Email: zhizhin@igic.ras.ru
Россия, Moscow, 107076
V. Retivov
Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”
Email: zhizhin@igic.ras.ru
Россия, Moscow, 107076
K. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry; Moscow Technological University (MITHT)
Автор, ответственный за переписку.
Email: zhizhin@igic.ras.ru
Россия, Moscow, 117907; Moscow, 119571
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: zhizhin@igic.ras.ru
Россия, Moscow, 117907
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