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Reaction of the [B10H9O2C4H8] anion with C-nucleophiles


Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The reactions of 1,4-dioxane-substituted closo-decaborate anion ([B10H9O2C4H8]) with metal acetylenides, diethyl malonate, ethyl acetoacetate, triethyl orthoformate, acetylacetone, and malonodinitrile were studied. The reactions were shown to be accompanied with substituent ring opening and attachment of the corresponding pendant functional group. The obtained compounds were characterized by various physicochemical methods (IR and polynuclear NMR spectroscopy, ESI mass spectrometry).

Авторлар туралы

E. Matveev

Kurnakov Institute of General and Inorganic Chemistry; Moscow Technological University (MITHT)

Email: zhizhin@igic.ras.ru
Ресей, Moscow, 117907; Moscow, 119571

S. Akimov

Chimmed Ltd.

Email: zhizhin@igic.ras.ru
Ресей, Moscow, 115230

A. Kubasov

Kurnakov Institute of General and Inorganic Chemistry

Email: zhizhin@igic.ras.ru
Ресей, Moscow, 117907

A. Nichugovskii

Moscow Technological University (MITHT)

Email: zhizhin@igic.ras.ru
Ресей, Moscow, 119571

A. Nartov

Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”

Email: zhizhin@igic.ras.ru
Ресей, Moscow, 107076

V. Retivov

Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”

Email: zhizhin@igic.ras.ru
Ресей, Moscow, 107076

K. Zhizhin

Kurnakov Institute of General and Inorganic Chemistry; Moscow Technological University (MITHT)

Хат алмасуға жауапты Автор.
Email: zhizhin@igic.ras.ru
Ресей, Moscow, 117907; Moscow, 119571

N. Kuznetsov

Kurnakov Institute of General and Inorganic Chemistry

Email: zhizhin@igic.ras.ru
Ресей, Moscow, 117907

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