Enviar artigo por via de e-mail Reaction of the [B10H9O2C4H8]– anion with C-nucleophiles
- Autores: Matveev E.Y.1,2, Akimov S.S.3, Kubasov A.S.1, Nichugovskii A.I.2, Nartov A.S.4, Retivov V.M.4, Zhizhin K.Y.1,2, Kuznetsov N.T.1
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Afiliações:
- Kurnakov Institute of General and Inorganic Chemistry
- Moscow Technological University (MITHT)
- Chimmed Ltd.
- Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”
- Edição: Volume 62, Nº 6 (2017)
- Páginas: 808-813
- Seção: Physical Methods of Investigation
- URL: https://bakhtiniada.ru/0036-0236/article/view/167769
- DOI: https://doi.org/10.1134/S0036023617060146
- ID: 167769
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Resumo
The reactions of 1,4-dioxane-substituted closo-decaborate anion ([B10H9O2C4H8]–) with metal acetylenides, diethyl malonate, ethyl acetoacetate, triethyl orthoformate, acetylacetone, and malonodinitrile were studied. The reactions were shown to be accompanied with substituent ring opening and attachment of the corresponding pendant functional group. The obtained compounds were characterized by various physicochemical methods (IR and polynuclear NMR spectroscopy, ESI mass spectrometry).
Sobre autores
E. Matveev
Kurnakov Institute of General and Inorganic Chemistry; Moscow Technological University (MITHT)
Email: zhizhin@igic.ras.ru
Rússia, Moscow, 117907; Moscow, 119571
S. Akimov
Chimmed Ltd.
Email: zhizhin@igic.ras.ru
Rússia, Moscow, 115230
A. Kubasov
Kurnakov Institute of General and Inorganic Chemistry
Email: zhizhin@igic.ras.ru
Rússia, Moscow, 117907
A. Nichugovskii
Moscow Technological University (MITHT)
Email: zhizhin@igic.ras.ru
Rússia, Moscow, 119571
A. Nartov
Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”
Email: zhizhin@igic.ras.ru
Rússia, Moscow, 107076
V. Retivov
Federal State Unitary Enterprise “Research Institute of Chemical Reagents and High-Purity Chemical Substances”
Email: zhizhin@igic.ras.ru
Rússia, Moscow, 107076
K. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry; Moscow Technological University (MITHT)
Autor responsável pela correspondência
Email: zhizhin@igic.ras.ru
Rússia, Moscow, 117907; Moscow, 119571
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: zhizhin@igic.ras.ru
Rússia, Moscow, 117907
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