Email this article Structural Features of Mononuclear Chelate Dioxomolybdenum(VI) Complexes with Tetradentate Chelate Ligands—Schiff Bases, Salicylaldehyde Derivatives [MOO2(Lm)] (m = 1−11)
- Authors: Sergienko V.S.1,2
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- All-Russian Institute for Scientific and Technical Information
- Issue: Vol 64, No 1 (2019)
- Pages: 36-40
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/169197
- DOI: https://doi.org/10.1134/S0036023619010182
- ID: 169197
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Abstract
The structural features of 12 chelate complexes with the general formula [MoO2(Lm)], where Lm is a tetradentate chelate (N, N, O, O) ligand representing a Schiff base, a salicylaldehyde derivative (m = 1−11), have been considered. In all 12 complexes, the molybdenum atom has a cis,cis,cis-octahedral coordination. Both pairs of N(Lm), O(Lm) atoms occupy both trans- and cis-positions to oxo ligands.
About the authors
V. S. Sergienko
Kurnakov Institute of General and Inorganic Chemistry; All-Russian Institute for Scientific and Technical Information
Author for correspondence.
Email: sergienko@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 125190
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