Structural Features of Mononuclear Chelate Dioxomolybdenum(VI) Complexes with Tetradentate Chelate Ligands—Schiff Bases, Salicylaldehyde Derivatives [MOO2(Lm)] (m = 1−11)

Resumo

The structural features of 12 chelate complexes with the general formula [MoO₂(L^m)], where L^m is a tetradentate chelate (N, N, O, O) ligand representing a Schiff base, a salicylaldehyde derivative (m = 1−11), have been considered. In all 12 complexes, the molybdenum atom has a cis,cis,cis-octahedral coordination. Both pairs of N(L^m), O(L^m) atoms occupy both trans- and cis-positions to oxo ligands.