Email this article Methanol transformations on framework lithium zirconium vanadate phosphates
- Authors: Ermilova M.M.1, Orekhova N.V.1, Mironova E.Y.1, Lytkina A.A.1, Pet’kov V.I.2, Shipilov A.S.2, Yaroslavtsev A.B.1,3
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Affiliations:
- Topchiev Institute of Petrochemical Synthesis
- Lobachevsky State University of Nizhny Novgorod
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 61, No 8 (2016)
- Pages: 940-945
- Section: Synthesis and Properties of Inorganic Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/166663
- DOI: https://doi.org/10.1134/S0036023616080076
- ID: 166663
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Abstract
The catalytic activity of framework phosphates of the general formula LiZr2(VO4)x(PO4)3–x with different degrees of phosphorus replacement (x = 0, 0.1, 0.3, 0.4, 0.6, and 0.8) was studied in methanol transformations in an inert atmosphere. It was shown that the ratio between the activity and selectivity of the catalysts in dehydration and dehydrogenation reactions is determined by their vanadium content and the process temperature.
About the authors
M. M. Ermilova
Topchiev Institute of Petrochemical Synthesis
Author for correspondence.
Email: ermilova@ips.ac.ru
Russian Federation, Leninskii pr. 29, Moscow, 119991
N. V. Orekhova
Topchiev Institute of Petrochemical Synthesis
Email: ermilova@ips.ac.ru
Russian Federation, Leninskii pr. 29, Moscow, 119991
E. Yu. Mironova
Topchiev Institute of Petrochemical Synthesis
Email: ermilova@ips.ac.ru
Russian Federation, Leninskii pr. 29, Moscow, 119991
A. A. Lytkina
Topchiev Institute of Petrochemical Synthesis
Email: ermilova@ips.ac.ru
Russian Federation, Leninskii pr. 29, Moscow, 119991
V. I. Pet’kov
Lobachevsky State University of Nizhny Novgorod
Email: ermilova@ips.ac.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
A. S. Shipilov
Lobachevsky State University of Nizhny Novgorod
Email: ermilova@ips.ac.ru
Russian Federation, pr. Gagarina 23, Nizhny Novgorod, 603950
A. B. Yaroslavtsev
Topchiev Institute of Petrochemical Synthesis; Kurnakov Institute of General and Inorganic Chemistry
Email: ermilova@ips.ac.ru
Russian Federation, Leninskii pr. 29, Moscow, 119991; Leninskii pr. 31, Moscow, 119991
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