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Methanol transformations on framework lithium zirconium vanadate phosphates


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Resumo

The catalytic activity of framework phosphates of the general formula LiZr2(VO4)x(PO4)3–x with different degrees of phosphorus replacement (x = 0, 0.1, 0.3, 0.4, 0.6, and 0.8) was studied in methanol transformations in an inert atmosphere. It was shown that the ratio between the activity and selectivity of the catalysts in dehydration and dehydrogenation reactions is determined by their vanadium content and the process temperature.

Sobre autores

M. Ermilova

Topchiev Institute of Petrochemical Synthesis

Autor responsável pela correspondência
Email: ermilova@ips.ac.ru
Rússia, Leninskii pr. 29, Moscow, 119991

N. Orekhova

Topchiev Institute of Petrochemical Synthesis

Email: ermilova@ips.ac.ru
Rússia, Leninskii pr. 29, Moscow, 119991

E. Mironova

Topchiev Institute of Petrochemical Synthesis

Email: ermilova@ips.ac.ru
Rússia, Leninskii pr. 29, Moscow, 119991

A. Lytkina

Topchiev Institute of Petrochemical Synthesis

Email: ermilova@ips.ac.ru
Rússia, Leninskii pr. 29, Moscow, 119991

V. Pet’kov

Lobachevsky State University of Nizhny Novgorod

Email: ermilova@ips.ac.ru
Rússia, pr. Gagarina 23, Nizhny Novgorod, 603950

A. Shipilov

Lobachevsky State University of Nizhny Novgorod

Email: ermilova@ips.ac.ru
Rússia, pr. Gagarina 23, Nizhny Novgorod, 603950

A. Yaroslavtsev

Topchiev Institute of Petrochemical Synthesis; Kurnakov Institute of General and Inorganic Chemistry

Email: ermilova@ips.ac.ru
Rússia, Leninskii pr. 29, Moscow, 119991; Leninskii pr. 31, Moscow, 119991

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