Synthesis of Dimethyl Phenylphosphonates Catalyzed by Group VI Metal(0) Hexacarbonyls


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The coupling of dimethyl phosphite and iodobenzene occurs in the presence of catalytic amounts of homoligand carbonyl complexes of chromium subgroup metals to form dimethyl phenylphosphonate in yields of 50–73% depending on the metal.

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A. Kuramshin

Kazan (Volga Region) Federal University

Email: fea_naro@mail.ru
俄罗斯联邦, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

A. Plotnikova

Kazan (Volga Region) Federal University

Email: fea_naro@mail.ru
俄罗斯联邦, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

M. Adel’shina

Kazan (Volga Region) Federal University

Email: fea_naro@mail.ru
俄罗斯联邦, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

V. Galkin

Kazan (Volga Region) Federal University

编辑信件的主要联系方式.
Email: fea_naro@mail.ru
俄罗斯联邦, ul. Kremlevskaya 18, Kazan, Tatarstan, 420008

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