Отправить статью по E-mail Reaction of difluoromethyl pentafluorophenyl sulfoxide with nucleophiles
- Авторы: Koshcheev B.V.1, Maksimov A.M.1, Platonov V.E.1, Shelkovnikov V.V.1
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Учреждения:
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Выпуск: Том 53, № 7 (2017)
- Страницы: 1012-1016
- Раздел: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/216524
- DOI: https://doi.org/10.1134/S1070428017070089
- ID: 216524
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Аннотация
Reactions of 1-(difluoromethanesulfinyl)pentafluorobenzene with sodium methoxide, sodium phenoxide, potassium hydrosulfide, and methylamine resulted in substitution of fluorine atom in the 4-position (in the reaction with methylamine, also in the 2-position). Treatment of the title compound with sodium hydroxide afforded pentafluorobenzene due to cleavage of the Carom‒S bond.
Об авторах
B. Koshcheev
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: platonov@nioch.nsc.ru
Россия, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
A. Maksimov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: platonov@nioch.nsc.ru
Россия, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
V. Platonov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Автор, ответственный за переписку.
Email: platonov@nioch.nsc.ru
Россия, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
V. Shelkovnikov
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
Email: platonov@nioch.nsc.ru
Россия, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090
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