Noncatalytic and Autocatalytic Rate Constants of the Reaction of Phenyl Isocyanate with Butan-1-ol
- Авторлар: Samuilov A.Y.1, Samuilov Y.D.1
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Мекемелер:
- Kazan National Research Technological University
- Шығарылым: Том 54, № 12 (2018)
- Беттер: 1749-1753
- Бөлім: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/219480
- DOI: https://doi.org/10.1134/S1070428018120011
- ID: 219480
Дәйексөз келтіру
Аннотация
The kinetics of the reaction of phenyl isocyanate with butan-1-ol have been studied in the temperature range from 30 to 60°C. The rate constants of the noncatalytic and autocatalytic reaction paths have been determined from the concentration dependences of the effective second-order rate constants. The autocatalytic reaction is characterized by lower enthalpies and entropies of activation than those of the noncatalytic reaction. The autocatalytic reaction is the major formation path of butyl phenylcarbamate.
Авторлар туралы
A. Samuilov
Kazan National Research Technological University
Email: ysamuilov@yandex.ru
Ресей, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
Ya. Samuilov
Kazan National Research Technological University
Хат алмасуға жауапты Автор.
Email: ysamuilov@yandex.ru
Ресей, ul. Karla Marksa 68, Kazan, Tatarstan, 420015
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