New Synthesis of Diethyl Trimethylsilyl Phosphite


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Abstract

Diethyl phosphonate rapidly reacted with hexamethyldisilazane at 20°C in the presence of 52 mol % of zinc(II) chloride to give 76% of diethyl trimethylsilyl phosphite.

About the authors

V. P. Morgalyuk

Nesmeyanov Institute of Organoelement Compounds

Author for correspondence.
Email: morgaliuk@mail.ru
Russian Federation, Moscow

T. V. Strelkova

Nesmeyanov Institute of Organoelement Compounds

Email: morgaliuk@mail.ru
Russian Federation, Moscow

A. G. Buyanovskaya

Nesmeyanov Institute of Organoelement Compounds

Email: morgaliuk@mail.ru
Russian Federation, Moscow

V. K. Brel

Nesmeyanov Institute of Organoelement Compounds

Email: morgaliuk@mail.ru
Russian Federation, Moscow

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