Email this article Synthesis of meta-Carboranyl-(S)-homocysteine Sulfoxide
- Authors: Gruzdev D.A.1, Ustinova V.O.1, Levit G.L.1, Ol’shevskaya V.A.2, Krasnov V.P.1
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Affiliations:
- Postovskii Institute of Organic Synthesis, Ural Branch
- Nesmeyanov Institute of Organoelement Compounds
- Issue: Vol 54, No 10 (2018)
- Pages: 1579-1582
- Section: Short Communications
- URL: https://bakhtiniada.ru/1070-4280/article/view/219348
- DOI: https://doi.org/10.1134/S1070428018100251
- ID: 219348
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Abstract
New (S)-homocysteine derivatives containing a meta-carborane fragment were synthesized. m-Carboranyl-(S)-homocysteine sulfoxide was obtained as a mixture of diastereoisomers. The reduction of the side-chain carboxy group of N-tert-butoxycarbonyl-(S)-aspartic acid α-tert-butyl ester with sodium tetrahydridoborate was not accompanied by racemization.
About the authors
D. A. Gruzdev
Postovskii Institute of Organic Synthesis, Ural Branch
Author for correspondence.
Email: gruzdev-da@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620990
V. O. Ustinova
Postovskii Institute of Organic Synthesis, Ural Branch
Email: gruzdev-da@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620990
G. L. Levit
Postovskii Institute of Organic Synthesis, Ural Branch
Email: gruzdev-da@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620990
V. A. Ol’shevskaya
Nesmeyanov Institute of Organoelement Compounds
Email: gruzdev-da@ios.uran.ru
Russian Federation, ul. Vavilova 28, Moscow, 119991
V. P. Krasnov
Postovskii Institute of Organic Synthesis, Ural Branch
Email: gruzdev-da@ios.uran.ru
Russian Federation, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620990
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