Email this article Synthesis of hydroxy derivatives from adamantanecarboxylic acids in the system MnO2–H2SO4
- Authors: Ivleva E.A.1, Gavrilova V.S.1, Klimochkin Y.N.1
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Affiliations:
- Samara State Technical University
- Issue: Vol 52, No 6 (2016)
- Pages: 785-790
- Section: Article
- URL: https://bakhtiniada.ru/1070-4280/article/view/214459
- DOI: https://doi.org/10.1134/S1070428016060051
- ID: 214459
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Abstract
A convenient procedure has been developed for the synthesis of mono- and dihydric cage alcohols from adamantanecarboxylic acids and their esters using the MnO2–H2SO4 system. The reaction at elevated temperature involved both decarboxylation and decarbonylation of the initial acid or ester.
About the authors
E. A. Ivleva
Samara State Technical University
Author for correspondence.
Email: elena.a.ivleva@yandex.com
Russian Federation, ul. Molodogvardeiskaya 244, Samara, 443100
V. S. Gavrilova
Samara State Technical University
Email: elena.a.ivleva@yandex.com
Russian Federation, ul. Molodogvardeiskaya 244, Samara, 443100
Yu. N. Klimochkin
Samara State Technical University
Email: elena.a.ivleva@yandex.com
Russian Federation, ul. Molodogvardeiskaya 244, Samara, 443100
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