Selective cycloaddition of aryl azides to fullerene C60 in the presence of Cu(OTf)2


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Abstract

Cycloaddition of aryl azides to fullerene C60 in the presence of a stoichiometric amount of copper(II) trifluoromethanesulfonate selectively afforded the corresponding aziridinofullerenes whose structure was reliably proved by 1H and 13C NMR, MALDI TOF mass spectrometry, and IR spectroscopy.

About the authors

A. R. Akhmetov

Institute of Petrochemistry and Catalysis

Author for correspondence.
Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075

A. R. Tuktarov

Institute of Petrochemistry and Catalysis

Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075

U. M. Dzhemilev

Institute of Petrochemistry and Catalysis

Email: ink@anrb.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075

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