Email this article Regio- and Stereoselective Addition of Selenium Dichloride to Alkyl Propiolates
- Authors: Musalov M.V.1, Yakimov V.A.1, Potapov V.A.1, Andreev M.V.1, Amosova S.V.1
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Affiliations:
- Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- Issue: Vol 55, No 11 (2019)
- Pages: 1809-1811
- Section: Short Communications
- URL: https://bakhtiniada.ru/1070-4280/article/view/221436
- DOI: https://doi.org/10.1134/S1070428019110277
- ID: 221436
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Abstract
The reaction of selenium dichloride with methyl and ethyl propiolates leads to formation of anti-Markovnikov adducts. The regio- and stereoselective synthesis of hitherto unknown bis[(E)-2-chloro-1-(alkoxycarbonyl)vinyl]selenides has been developed based on this reaction.
About the authors
M. V. Musalov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
V. A. Yakimov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
V. A. Potapov
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Author for correspondence.
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
M. V. Andreev
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
S. V. Amosova
Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: v_a_potapov@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033
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