Email this article Synthesis of β-Lactam and Anomalous Minor Products in the (i-Pr)2NEt-Promoted Reaction of N-Chloroglycine Methyl Ester Derivative with Dichloroacetyl Chloride
- Authors: Valiullina Z.R.1, Galeeva A.M.1, Selezneva N.K.1, Miftakhov M.S.1
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Affiliations:
- Ufa Institute of Chemistry, Ufa Federal Research Center
- Issue: Vol 54, No 10 (2018)
- Pages: 1559-1561
- Section: Short Communications
- URL: https://bakhtiniada.ru/1070-4280/article/view/219310
- DOI: https://doi.org/10.1134/S1070428018100196
- ID: 219310
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Abstract
Apart from the expected [2 + 2]-cycloaddition product, the reaction of N-chloro-N-(2-methoxy-2-oxoethyl)-β-alanine methyl ester with dichloroacetyl chloride in the presence of ethyl(diisopropyl)amine gave minor N-(1,2-dichloro-2-oxoethyl)-β-alanine methyl ester and (3E)-1,1,1-trichloro-4-(diisopropylamino)- but-3-en-2-one.
About the authors
Z. R. Valiullina
Ufa Institute of Chemistry, Ufa Federal Research Center
Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054
A. M. Galeeva
Ufa Institute of Chemistry, Ufa Federal Research Center
Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054
N. K. Selezneva
Ufa Institute of Chemistry, Ufa Federal Research Center
Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054
M. S. Miftakhov
Ufa Institute of Chemistry, Ufa Federal Research Center
Author for correspondence.
Email: bioreg@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054
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