Unusual Reaction of 1,3-Benzothiazole-2-thiol with Iodomethyl(dimethyl)phenylsilane in the Presence of Iodine


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Abstract

The three-component reaction of 1,3-benzothiazole-2-thiol with iodomethyl(dimethyl)phenylsilane and molecular iodine in the absence of a base and phase-transfer catalyst afforded 2-[(dimethyl(phenyl)-silylmethylsulfanyl]-1,3-benzothiazolium triiodide and 2,2-dimethyl-2,3-dihydro[1,4,2]thiazasilolo[5,4-b][1,3]-benzothiazolium triiodide.

About the authors

N. O. Yarosh

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Author for correspondence.
Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

L. V. Zhilitskaya

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

L. G. Shagun

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

I. A. Dorofeev

Favorskii Irkutsk Institute of Chemistry, Siberian Branch

Email: yarosh.nina@irioch.irk.ru
Russian Federation, ul. Favorskogo 1, Irkutsk, 664033

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