Unusual Reaction of 1,3-Benzothiazole-2-thiol with Iodomethyl(dimethyl)phenylsilane in the Presence of Iodine

Аннотация

The three-component reaction of 1,3-benzothiazole-2-thiol with iodomethyl(dimethyl)phenylsilane and molecular iodine in the absence of a base and phase-transfer catalyst afforded 2-[(dimethyl(phenyl)-silylmethylsulfanyl]-1,3-benzothiazolium triiodide and 2,2-dimethyl-2,3-dihydro[1,4,2]thiazasilolo[5,4-b][1,3]-benzothiazolium triiodide.