Photochromism of 3H-2,1,4-benzoxadiazine 4-oxides with heterocyclic substituents on the benzene ring


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Аннотация

2H-Benzimidazole 1,3-dioxides undergo thermal isomerization to 3H-2,1,4-benzoxadiazine 4-oxides which are converted to 2H-benzimidazole 1-oxides on further heating. Irradiation of 3H-2,1,4-benzoxadiazine 4-oxides with sunlight induces their transformation to 2H-benzimidazole 1,3-dioxides. 3H-2,1,4-Benzoxadiazine 4-oxides containing nucleophilic heterocyclic substituents are considerably more stable to sunlight, and they can be used as photochromic compounds.

Авторлар туралы

E. Chugunova

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Хат алмасуға жауапты Автор.
Email: elena-chugunova@list.ru
Ресей, ul. Arbuzova 8, Kazan Tatarstan, 420088

N. Akylbekov

Kazan National Research Technological University

Email: elena-chugunova@list.ru
Ресей, ul. Karla Marksa 68, Kazan Tatarstan, 420015

V. Samsonov

Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch

Email: elena-chugunova@list.ru
Ресей, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090

S. Sitnov

Kazan Federal University

Email: elena-chugunova@list.ru
Ресей, ul. Kremlevskaya 18, Kazan Tatarstan, 420008

A. Burilov

Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center

Email: elena-chugunova@list.ru
Ресей, ul. Arbuzova 8, Kazan Tatarstan, 420088

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