Reaction of 2-{[2-(ethenyloxy)ethoxy]methyl}oxirane with oxazolidin-2-ones

N. A. Lobanova; E. Kh. Sadykov; V. K. Stankevich

doi:10.1134/S1070428016040138

Reaction of 2-{[2-(ethenyloxy)ethoxy]methyl}oxirane with oxazolidin-2-ones

Authors: Lobanova N.A.¹, Sadykov E.K.¹, Stankevich V.K.¹
Affiliations:
1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Issue: Vol 52, No 4 (2016)
Pages: 553-557
Section: Review
URL: https://bakhtiniada.ru/1070-4280/article/view/214121
DOI: https://doi.org/10.1134/S1070428016040138
ID: 214121

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Abstract

Reactions of 2-{[2-(ethenyloxy)ethoxy]methyl}oxirane with N-unsubstituted oxazolidin-2-ones give mixtures of isomeric 3-{3-[2-(ethenyloxy)ethoxy]-2-hydroxypropyl}- and 5-{[2-(ethenyloxy)ethoxy]- methyl}-3-(2-hydroxyalkyl)oxazolidin-2-ones. If the initial oxazolidin-2-one contains two alkyl groups on C⁴, 3-{3-[2-(ethenyloxy)ethoxy]-2-hydroxypropyl}oxazolidin-2-ones are selectively formed.