Effect of Association on Nucleophilic Addition of (Meth)acrylic Aminoamides to Acrylic Acids in Aqueous Solutions


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Resumo

Reactions of nucleophilic addition of N-(3-dimethylaminoalkyl)(meth)acrylamides to acrylic, N-acryloylaminoacetic, and 2-acrylamido-2-methylpropanesulfonic acid with the formation of betaines revealed an unusual dependence of the initial rate and equilibrium conversion on concentration of the reagents. The observed effects were explained by structural features of the reagents and the products.

Sobre autores

О. Kazantsev

R.E. Alekseev Nizhny Novgorod State Technical University

Email: kkshirshin@mail.ru
Rússia, ul. Minina 24, Nizhny Novgorod, 603950

D. Baruta

R.E. Alekseev Nizhny Novgorod State Technical University

Email: kkshirshin@mail.ru
Rússia, ul. Minina 24, Nizhny Novgorod, 603950

D. Kamorin

R.E. Alekseev Nizhny Novgorod State Technical University

Email: kkshirshin@mail.ru
Rússia, ul. Minina 24, Nizhny Novgorod, 603950

K. Shirshin

R.E. Alekseev Nizhny Novgorod State Technical University; N.I. Lobachevsky State University of Nizhny Novgorod

Autor responsável pela correspondência
Email: kkshirshin@mail.ru
Rússia, ul. Minina 24, Nizhny Novgorod, 603950; Nizhny Novgorod

А. Sivokhin

R.E. Alekseev Nizhny Novgorod State Technical University

Email: kkshirshin@mail.ru
Rússia, ul. Minina 24, Nizhny Novgorod, 603950

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