Synthesis of trivalent phosphorus derivatives by light-induced dibromophosphination of akenes


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Abstract

Light-induced dibromophosphination of alkenes was studied. Dehydrobromination of the synthesized bromoalkylphosphonous dibromides gave the corresponding dibromophosphinoalkenes which were converted into alkenylphosphonous acids and their cyclic esters, benzo[1,3,2]dioxaphospholes.

About the authors

M. N. Krivchun

St. Petersburg State Institute of Technology (Technical University)

Author for correspondence.
Email: maxim1960@mail.ru
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013

A. V. Khramchikhin

St. Petersburg State Institute of Technology (Technical University)

Email: maxim1960@mail.ru
Russian Federation, Moskovskii pr. 26, St. Petersburg, 190013

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