CuCl2-Mediated Hydroxylation of 2,3-Dimethyl-5-hydroxy-6-aminopyrimidine-4(3H)-one with Molecular Oxygen in Aqueous and Non-Aqueous Solutions


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Abstract

The catalytic hydroxylation of 2,3-dimethyl-5-hydroxy-6-aminopyrimidine-4(3H)-one in an aqueous solution in the presence of copper(II) ions and oxygen proceeds with the formation of 2,3-dimethyl-5,5,6-trihydroxy-6-aminopyrimidine-4-(3H)-one.

About the authors

V. Yu. Mishinkin

Ufa Institute of Chemistry

Email: murinov@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, 450054

S. A. Grabovskii

Ufa Institute of Chemistry

Email: murinov@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, 450054

N. N. Kabal’nova

Ufa Institute of Chemistry

Email: murinov@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, 450054

Yu. I. Murinov

Ufa Institute of Chemistry

Author for correspondence.
Email: murinov@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, 450054

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