Synthesis of 8-Methyl-5-[(methylsulfanyl)methyl]-3-thiabicyclo[3.3.1]non-7-en-6-one and Its Extraction Ability for Gold(III)


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Abstract

An efficient one-pot procedure has been proposed for the synthesis of 8-methyl-5-[(methylsulfanyl) methyl]-3-thiabicyclo[3.3.1]non-7-en-6-one from accessible natural raw materials. A stable complex of the title compound with gold(III) has been obtained by the extraction method, and the mode of its coordination to the metal ion has been determined by IR and NMR spectroscopy.

About the authors

L. G. Golubyatnikova

Ufa Institute of Chemistry

Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054

R. A. Khisamutdinov

Ufa Institute of Chemistry

Author for correspondence.
Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054

L. A. Baeva

Ufa Institute of Chemistry

Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054

Yu. I. Murinov

Ufa Institute of Chemistry

Email: hisam@anrb.ru
Russian Federation, pr. Oktyabrya 69, Ufa, Bashkortostan, 450054

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